Electrons and Photons
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1. Important Constants and Symbols
| Quantity | Symbol | Value / unit |
|---|---|---|
| Electronic charge magnitude | e | 1.602 × 10⁻¹⁹ C |
| Electron mass | me | 9.11 × 10⁻³¹ kg |
| Specific charge of electron | e/m | ≈ 1.76 × 10¹¹ C kg⁻¹ |
| Planck constant | h | 6.626 × 10⁻³⁴ J s |
| Speed of light | c | 3.00 × 10⁸ m s⁻¹ |
| Electron-volt | eV | 1 eV = 1.602 × 10⁻¹⁹ J |
2. Electron: Basic Properties
- Charge: −1.602 × 10⁻¹⁹ C.
- Rest mass: 9.11 × 10⁻³¹ kg.
- Charge-to-mass magnitude: e/m ≈ 1.76 × 10¹¹ C kg⁻¹.
- Its motion is affected by electric and magnetic fields.
3. Millikan’s Oil-Drop Experiment
3.1 Main Apparatus
- Two parallel horizontal metal plates separated by a small distance.
- Potential difference across plates to produce a nearly uniform electric field.
- Atomizer producing tiny oil droplets.
- Illumination and microscope for observing droplets.
- Ionizing source used to alter droplet charge when required.
Diagram 1: Simplified Millikan oil-drop apparatus and force balance
3.2 Radius of the Oil Drop
First allow a drop of radius r and density ρ to fall through air of density σ. At terminal speed v1:
effective weight = viscous drag (4/3)πr³(ρ − σ)g = 6πηrv₁Therefore,
3.3 Charge on a Rising Drop
If the electric field causes a negatively charged drop to rise with terminal speed v2, the electric force balances effective weight plus viscous drag:
qE = (4/3)πr³(ρ − σ)g + 6πηrv₂Using the falling condition,
If plate separation is d and potential difference is V:
E = V/d4. Quantization of Electric Charge
n = 0, 1, 2, 3, … and e = 1.602 × 10⁻¹⁹ C.
Diagram 2: Discrete charge values
5. Motion of an Electron in an Electric Field
5.1 Electric Force and Acceleration
For a charge q in uniform electric field E:
F = qEFor an electron, the force direction is opposite to E. The magnitude of acceleration is:
5.2 Electron Entering Perpendicular to E
Suppose an electron enters with horizontal speed u and the electric field is vertical. Horizontal acceleration is zero while vertical acceleration is constant.
x = ut y = (1/2)(eE/m)t²Eliminating t = x/u gives:
This is an equation of a parabola.
Diagram 3: Parabolic path in a transverse electric field
6. Motion of an Electron in a Magnetic Field
6.1 Magnetic Force
Magnitude of magnetic force on a charge moving with velocity v at angle θ to B:
6.2 Electron Moving Perpendicular to B
For θ = 90°, magnetic force provides centripetal force:
evB = mv²/rHence:
6.3 Time Period and Frequency
T = 2πr/vUsing r = mv/(eB):
In the non-relativistic model, the period and frequency are independent of the electron speed.
Diagram 4: Circular motion in a perpendicular magnetic field
7. Electron in Crossed Electric and Magnetic Fields
If electric and magnetic fields are mutually perpendicular and the electron beam is undeflected, the electric and magnetic forces have equal magnitudes:
eE = evBThis arrangement acts as a velocity selector: only particles with speed E/B pass undeflected.
Diagram 5: Electric and magnetic forces cancel for selected speed
8. J.J. Thomson’s Experiment and Specific Charge of Electron
J.J. Thomson studied the deflection of cathode-ray electrons in electric and magnetic fields and determined their specific charge.
8.1 Velocity from Crossed Fields
8.2 Magnetic Deflection
With magnetic field alone producing a circular path of radius r:
evB = mv²/rTherefore:
Diagram 6: Conceptual Thomson specific-charge method
9. Quantum Nature of Radiation and Photons
Classical wave theory successfully describes interference, diffraction and polarization, but the photoelectric effect requires energy exchange in discrete packets.
9.1 Properties of Photons
- Photon energy is E = hf.
- Photon momentum is p = h/λ.
- Photons have zero rest mass.
- They carry no electric charge.
- In vacuum they move at speed c.
- They are not deflected by ordinary electric or magnetic fields.
- Energy transfer in light–matter interactions can occur photon by photon.
Diagram 7: Energy carried by a photon
10. Photoelectric Effect
The emitted electrons are called photoelectrons.
10.1 Work Function
f0 is the threshold frequency and λ0 is the threshold wavelength.
10.2 Threshold Frequency
If f < f0, no photoelectron is emitted, regardless of how intense the light is in the ideal single-photon model.
Diagram 8: Simplified photoelectric cell
11. Experimental Laws of the Photoelectric Effect
- Threshold frequency exists: below f0, photoemission does not occur.
- Photoelectric current depends on intensity: for frequency above threshold, increasing light intensity generally increases the number of emitted electrons per second and hence saturation current.
- Maximum kinetic energy depends on frequency: increasing frequency increases Kmax and stopping potential.
- Kinetic energy is not controlled by intensity: intensity mainly changes the number of photons/electrons, not the maximum energy per emitted electron.
- Emission is essentially immediate: there is no classical energy-accumulation delay at sufficiently high frequency.
12. Einstein’s Photoelectric Equation
Einstein applied Planck’s quantum concept: one photon transfers energy hf to one electron.
photon energy = work function + maximum electron kinetic energySince φ = hf0:
Using stopping potential Vs:
Diagram 9: Photon energy is divided between escape work and kinetic energy
13. Stopping Potential
Combining with Einstein’s equation:
Thus a graph of Vs versus f is a straight line with:
- Slope = h/e
- Frequency-axis intercept = f0
14. Millikan’s Photoelectric Experiment and Planck’s Constant
Millikan carefully measured stopping potential for different light frequencies and verified Einstein’s linear photoelectric equation.
eVs = hf − φRearranging:
Vs = (h/e)f − φ/eIf the slope of the Vs-versus-f graph is S:
Diagram 10: Stopping potential varies linearly with frequency
15. Important Photoelectric Graphs
15.1 Photocurrent vs Applied Potential: Effect of Intensity
At the same frequency above threshold, higher light intensity produces a larger saturation current because more photons arrive per second and more electrons are emitted.
Diagram 11: Intensity changes saturation photocurrent
15.2 Effect of Frequency
At comparable intensity, increasing frequency increases maximum electron kinetic energy, so a larger stopping potential magnitude is needed.
Diagram 12: Frequency changes stopping potential
16. Worked Numericals
An electron moves at 3.0 × 10⁶ m/s perpendicular to a magnetic field of 0.020 T. Find the radius.
r = mv/(eB) r = (9.11 × 10⁻³¹ × 3.0 × 10⁶)/(1.602 × 10⁻¹⁹ × 0.020) r ≈ 8.53 × 10⁻⁴ mE = 3.0 × 10⁴ V/m and B = 2.0 × 10⁻³ T. Find the speed of an undeflected electron.
v = E/B v = (3.0 × 10⁴)/(2.0 × 10⁻³) v = 1.5 × 10⁷ m/sFind the energy of a 500 nm photon.
E = hc/λ E = (6.626 × 10⁻³⁴)(3.00 × 10⁸)/(500 × 10⁻⁹) E ≈ 3.98 × 10⁻¹⁹ J ≈ 2.48 eVA metal has work function 2.0 eV and receives photons of energy 3.5 eV.
Kmax = 3.5 − 2.0 = 1.5 eVTherefore:
Vₛ = 1.5 VWork function φ = 3.0 eV.
φ = 3.0 × 1.602 × 10⁻¹⁹ = 4.806 × 10⁻¹⁹ J f₀ = φ/h ≈ 7.25 × 10¹⁴ HzThe slope of a stopping-potential versus frequency graph is 4.14 × 10⁻¹⁵ V·s.
h = e × slope h = (1.602 × 10⁻¹⁹)(4.14 × 10⁻¹⁵) h ≈ 6.63 × 10⁻³⁴ J·sA droplet carries charge 4.806 × 10⁻¹⁹ C.
n = q/e = 4.806/1.602 = 3The drop carries 3 elementary charges.
17. Formula Sheet
| Topic | Formula |
|---|---|
| Charge quantization | q = ne |
| Electric force | F = qE |
| Electron acceleration in E | a = eE/m |
| Transverse electric path | y = eEx²/(2mu²) |
| Magnetic force | F = evB sinθ |
| Magnetic circular radius | r = mv/(eB) |
| Cyclotron period | T = 2πm/(eB) |
| Cyclotron frequency | f = eB/(2πm) |
| Velocity selector | v = E/B |
| Specific charge | e/m = E/(B²r) |
| Photon energy | E = hf = hc/λ |
| Photon momentum | p = h/λ |
| Work function | φ = hf₀ = hc/λ₀ |
| Einstein equation | hf = φ + Kmax |
| Stopping potential | Kmax = eVₛ |
| Vₛ-frequency line | Vₛ = (h/e)f − φ/e |
| Planck constant from slope | h = e(dVₛ/df) |
18. Common Exam Mistakes
- Using the electron charge as +e when discussing force direction. The electron charge is negative.
- Forgetting buoyancy/effective weight in a careful Millikan oil-drop derivation.
- Writing charge as any continuous value instead of q = ne.
- Using v = E/B when electric and magnetic forces are not in the correct crossed-field configuration.
- Writing magnetic force as evB for every angle; the full form is evB sinθ.
- Claiming a magnetic field changes the electron’s speed in uniform circular motion. It mainly changes direction because magnetic force does no work.
- Forgetting that r ∝ v/B for fixed particle.
- Confusing e/m with m/e.
- Writing photon energy as h/f. Correct: E = hf.
- Writing photon momentum as hλ. Correct: p = h/λ.
- Confusing intensity with frequency in the photoelectric effect.
- Claiming high intensity can produce photoelectrons below threshold frequency.
- Forgetting the work function in Einstein’s equation.
- Using stopping potential as an accelerating potential. It is the reverse potential that just stops the most energetic photoelectrons.
- Writing φ = h/ f₀ instead of φ = hf₀.
- Forgetting that the slope of Vₛ versus f is h/e, not h alone.
- Using wavelength in nm without converting to metres in SI calculations.
- Using eV directly with h in J·s without converting units consistently.
19. Important Exam Questions
Chapter 20: Electrons — Short Questions
- State the charge and mass of an electron.
- What is quantization of charge?
- State the purpose of Millikan’s oil-drop experiment.
- Why is a non-volatile oil used in Millikan’s experiment?
- Write the force balance for a freely falling oil drop at terminal speed.
- Derive the expression for the radius of an oil drop.
- Show how Millikan’s experiment establishes q = ne.
- What is the force on an electron in an electric field?
- Show that an electron entering a transverse uniform electric field follows a parabolic path.
- Write the magnetic force on a moving electron.
- Derive r = mv/(eB).
- Show that the time period of circular motion in a uniform magnetic field is independent of speed.
- Derive the velocity-selector relation v = E/B.
- Define specific charge.
- Explain the principle of J.J. Thomson’s experiment.
- Derive e/m = E/(B²r).
Chapter 21: Photons — Short Questions
- What is a photon?
- State the quantum nature of electromagnetic radiation.
- Write any four properties of photons.
- Derive p = h/λ for a photon.
- Define work function.
- Define threshold frequency.
- Define photoelectric effect.
- State the laws of photoelectric emission.
- How does intensity affect photoelectric current?
- How does frequency affect maximum kinetic energy?
- State Einstein’s photoelectric equation.
- Define stopping potential.
- Show that Kmax = eVₛ.
- Derive Vₛ = (h/e)f − φ/e.
- How did Millikan verify Einstein’s photoelectric equation?
- How can Planck’s constant be determined from the Vₛ–f graph?
Long Questions / Derivations
- Describe Millikan’s oil-drop experiment and explain quantization of charge.
- Derive the expression for charge on a rising oil drop.
- Derive the equation of the path of an electron in a transverse electric field.
- Derive radius, period and frequency of an electron moving perpendicular to a uniform magnetic field.
- Describe J.J. Thomson’s experiment and derive the electron’s specific charge.
- Explain the quantum nature of radiation and properties of photons.
- Explain the photoelectric effect and its experimental laws.
- Derive Einstein’s photoelectric equation.
- Explain stopping potential and threshold frequency.
- Describe Millikan’s photoelectric experiment and determination of Planck’s constant.
Numerical Practice
- Find charge on an oil drop and express it as a multiple of e.
- Calculate electron radius in a magnetic field.
- Calculate electron cyclotron frequency.
- Find undeflected velocity in crossed fields.
- Calculate e/m from E, B and r.
- Calculate photon energy from wavelength or frequency.
- Convert photon energy between joules and electron-volts.
- Calculate threshold frequency or threshold wavelength from work function.
- Calculate Kmax and stopping potential.
- Find Planck’s constant from the slope of a stopping-potential graph.
20. One-Minute Revision
- Electron charge = −1.602 × 10⁻¹⁹ C.
- Electron mass = 9.11 × 10⁻³¹ kg.
- Charge is quantized: q = ne.
- Millikan’s oil-drop experiment measured elementary charge.
- For falling oil drop: effective weight = Stokes drag.
- Uniform electric field gives electron acceleration magnitude eE/m.
- Electron entering transverse E follows a parabola.
- Magnetic force magnitude = evB sinθ.
- For v ⟂ B, electron moves in a circle of radius mv/(eB).
- Magnetic period T = 2πm/(eB).
- Crossed-field undeflected speed v = E/B.
- J.J. Thomson measured electron specific charge e/m.
- Photon energy = hf = hc/λ.
- Photon momentum = h/λ.
- Photon rest mass = 0 and charge = 0.
- Photoelectric effect emits electrons when f ≥ f₀.
- Work function φ = hf₀.
- Intensity mainly changes photocurrent.
- Frequency changes Kmax and stopping potential.
- Einstein equation: hf = φ + Kmax.
- Kmax = ½mvmax² = eVₛ.
- Stopping potential is the reverse potential that reduces photocurrent to zero.
- Vₛ = (h/e)f − φ/e.
- Slope of Vₛ vs f = h/e.
- Planck constant can be obtained from h = e × slope.
21. Diagram Practice
Students should practice these labelled diagrams for the NEB examination:
- Millikan oil-drop apparatus and forces.
- Quantization-of-charge diagram.
- Electron path in transverse electric field.
- Electron circular motion in magnetic field.
- Crossed E and B velocity selector.
- J.J. Thomson specific-charge apparatus concept.
- Photon energy/wavelength diagram.
- Photoelectric cell arrangement.
- Einstein photoelectric energy balance.
- Stopping potential vs frequency graph.
- Photocurrent vs potential for different intensities.
- Photocurrent vs potential for different frequencies.
Discussion
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